The ad break in this episode occurs around the 00:31:25 mark. This is indicated by the host saying, "All right, this is a good time for us to take a break," followed by a transition to the next segment.

Recommendations

Q: where is the ad break in this episode?

They Call Us Bruce:
They Call Us AfrAId

Q: where is the ad break in this episode?

They Call Us Bruce:
They Call Us Dìdi (弟弟)

Q: is there an ad break in this episode?

Modern Minorities:
Star Wars: the Fourth with you (maybe?)